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Preheat oven to 200 degrees. Remove film. Pour 1/4 of a cup of water onto the pearl barley and drizzle the chicken with some olive oil. DEFROSTED: Cover with foil, cook for 15 minutes, then remove the foil and cook uncovered for a further 20 minutes or until chicken and pearl barley are piping hot. FROZEN: Cover with foil, cook for 35 minutes, then remove the foil and cook uncovered for a further 20 minutes or until the chicken and pearl barley are piping hot.